CO2 hydrogenation to acetic acid and methyl acetate via tandem catalysis

SY Han and LH He and N Chen and D Fan and P Tian and ZM Liu, NATURE COMMUNICATIONS, 16, 11250 (2025).

DOI: 10.1038/s41467-025-66117-9

Selective hydrogenation of CO2 into high-value C2+ oxygenates, such as acetic acid (AA), methyl acetate (MA), and ethanol, is highly attractive yet remains a significant challenge. This study demonstrates an innovative tandem catalysis system for converting CO2 to AA and MA, employing GaZrOx and hydrophobically modified MOR-8-C1@PC (PTFE+CNTs) catalysts. The upstream GaZrOx drives CO2 hydrogenation to produce an effluent gas with a controlled CO/(DME + CH3OH) ratio of approximately 4, facilitating the subsequent carbonylation reaction over the MOR-based catalyst. For the downstream catalyst, surface silanization of MOR zeolite combined with a hydrophobic promoter effectively prevents water (generated during CO2 hydrogenation) from entering the zeolite channels and greatly enhances the carbonylation activity and catalyst stability. Results show that at a CO2 conversion of 27%, the selectivity towards AA and MA in the organics reaches up to 78%, with no catalyst deactivation observed over 50 hours. This strategy offers an efficient approach for converting CO2 into C2+ oxygenates, with promising implications for sustainable chemical production.

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