Achieving ultra-high anisotropy in thermal conductivity of plastic crystals through megapascal pressure via hot pressing

ZP Wu and MZ Fan and YJ Qin and GZ Zhang and N Yang, JOURNAL OF MATERIALS CHEMISTRY C, 13, 5180-5188 (2025).

DOI: 10.1039/d4tc02835j

Plastic crystals, owing to their exceptional properties, are gradually finding applications in solid-state refrigeration and ferroelectric fields. However, their inherently low thermal conductivity restricts their utilization in electronic devices. This study demonstrates that applying megapascal pressure via hot pressing can enhance the thermal conductivity of plastic crystal films. Most importantly, it induces significant anisotropy in thermal conductivity. Such anisotropy in thermal conductivity is beneficial for specialized thermal management applications, such as directing heat flow paths in electronic devices. In this study, (CH3)4NFeCl4 PC films were prepared via hot pressing. At a pressure of 16 MPa, the ratio of in-plane to cross-plane thermal conductivity in the film reaches a remarkable 5.5. This is attributed to the preferential orientation along the (002) crystal plane induced by uniaxial pressure, leading to the formation of a layered structure and the creation of a flat and dense film. Furthermore, according to molecular dynamics simulations, the thermal conductivity along the 100 and 010 directions (parallel to the (002) crystal plane) is higher than in other directions. Therefore, significant modulation of anisotropy in thermal conductivity is achieved in (CH3)4NFeCl4 films by applying uniaxial hot pressing pressure. This phenomenon has the potential to greatly broaden the application of plastic crystals in the field of flexible electronic devices.

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