Nanofluid-Guided Janus Membrane for High-Efficiency Electricity Generation from Water Evaporation

YX Han and YL Wang and M Wang and H Dong and Y Nie and SJ Zhang and HY He, ADVANCED MATERIALS, 36 (2024).

DOI: 10.1002/adma.202312209

Harvesting electricity from widespread water evaporation provides an alternative route to cleaner power generation technology. However, current evaporation power generation (EPG) mainly depends on the dissociation process of certain functional groups (e.g., SO3H) in water, which suffers from low power density and short-term output. Herein, the Janus membrane is prepared by combining nanofluid and water-grabbing material for EPG, where the nanoconfined ionic liquids (NCILs) serve as ion sources instead of the functional groups. Benefiting from the selective and fast transport of anions in NCILs, such EPG demonstrates excellent power performance with a voltage of 0.63 V, a short-circuit current of 140 mu A, and a maximum power density of 16.55 mu W cm-2 while operating for at least 180 h consistently. Molecular dynamics (MD) simulation and surface potential analysis reveal the molecular mechanism, that is, the diffusion of Cl- anions during evaporation is much faster than that of cations, generating the voltage and current across the membrane. Furthermore, the device performs well in varying environmental conditions, including different water temperatures and sources of evaporating water, showcasing its adaptability and integrability. Overall, the nanofluid-guided Janus membrane can efficiently transform low-grade thermal energy in evaporation into electricity, showing a competitive advantage over other sustainable applied approaches. The nanoconfined ionic liquids-guided evaporation power generator achieves high-efficiency performance with an open- circuit voltage of 0.63 V, a short-circuit current of 140 mu A, and an ultra-high continuous operating time of 180 h, providing a new strategy for clean power generation technologies. image

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