Structural transition and migration of incoherent twin boundary in diamond

K Tong and X Zhang and ZH Li and YB Wang and K Luo and CM Li and TY Jin and YQ Chang and S Zhao and YJ Wu and YF Gao and BZ Li and GY Gao and ZS Zhao and L Wang and AM Nie and DL Yu and ZY Liu and AV Soldatov and WT Hu and B Xu and YJ Tian, NATURE, 626 (2024).

DOI: 10.1038/s41586-023-06908-6

Grain boundaries (GBs), with their diversity in both structure and structural transitions, play an essential role in tailoring the properties of polycrystalline materials1-5. As a unique GB subset, 112 incoherent twin boundaries (ITBs) are ubiquitous in nanotwinned, face- centred cubic materials6-9. Although multiple ITB configurations and transitions have been reported7,10, their transition mechanisms and impacts on mechanical properties remain largely unexplored, especially in regard to covalent materials. Here we report atomic observations of six ITB configurations and structural transitions in diamond at room temperature, showing a dislocation-mediated mechanism different from metallic systems11,12. The dominant ITBs are asymmetric and less mobile, contributing strongly to continuous hardening in nanotwinned diamond13. The potential driving forces of ITB activities are discussed. Our findings shed new light on GB behaviour in diamond and covalent materials, pointing to a new strategy for development of high- performance, nanotwinned materials. We report atomic observations of six incoherent twin boundary configurations and structural transitions in diamond at room temperature, showing a dislocation-mediated mechanism different from metallic systems and shedding new light on grain boundary behaviour.

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