Micron-Thick Interlocked Carbon Nanotube Films with Excellent Impact Resistance via Micro-Ballistic Impact
KL Xiao and PF Zhang and DM Hu and CG Huang and XQ Wu, SMALL, 19 (2023).
DOI: 10.1002/smll.202302403
The highest specific energy absorption (SEA) of interlocked micron- thickness carbon nanotube (IMCNT) films subjected to micro-ballistic impact is reported in this paper. The SEA of the IMCNT films ranges from 0.8 to 1.6 MJ kg(-1), the greatest value for micron-thickness films to date. The multiple deformation-induced dissipation channels at the nanoscale involving disorder-to-order transition, frictional sliding, and entanglement of CNT fibrils contribute to the ultra-high SEA of the IMCNT. Furthermore, an anomalous thickness dependency of the SEA is observed, that is, the SEA increases with increasing thickness, which should be ascribed to the exponential growth in nano-interface that further boosts the energy dissipation efficiency as the film thickness increases. The results indicate that the developed IMCNT overcomes the size-dependent impact resistance of traditional materials and demonstrates great potential as a bulletproof material for high- performance flexible armor.
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