Microstructure characteristics and failure mechanisms of Ti-48Al-2Nb-2Cr titanium aluminide intermetallic alloy fabricated by directed energy deposition technique

JW Wang and Q Luo and HM Wang and Y Wu and X Cheng and HB Tang, ADDITIVE MANUFACTURING, 32, 101007 (2020).

DOI: 10.1016/j.addma.2019.101007

The high-energy input and thermal history during additive manufacturing lead to complex phase transformations in titanium aluminide alloy. This study mostly focuses on determining the solid-state phase transformation mechanisms during laser deposition and the failure mechanisms of alloys using molecular dynamics simulations. Because of the directional temperature gradient, columnar grains with fully lamellar microstructures are formed first after solidification. A narrow region just below the melting pool is reheated to high temperatures, thus enhancing the precipitation of new equiaxed grains. Multiple thermal cycles in the alpha + gamma phase region promote the formation of massive gamma phases (gamma(m)) at the grain boundaries. Finally, a nearly lamellar microstructure of alternating columnar and equiaxed grains with y m phases is formed. The deposited titanium aluminide alloy has good room and high-temperature (760 degrees C) tensile properties of 545 +/- 9 and 471 +/- 37 MPa, with elongations of 1.50 % +/- 0.47 % and 1.50 % +/- 0.45 %, respectively. The room and high-temperature samples both fail in the columnar grain region. The molecular dynamics simulations suggest that the interface between alpha(2) and gamma(m) is the weakest, especially in the case of semicoherent interfaces (6 degrees angle in the 1-10 direction), which provides good nucleation sites for cracks. Although the equiaxed grain regions contain several gamma(m)-alpha(2) interfaces, the samples still fail in the columnar grain regions due to the increase in the cracking distance in the equiaxed regions caused by randomly oriented alpha(2) + gamma lamellae and the comparably good plasticity of the gamma(m) phases.

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